Courses:

Help support MIT OpenCourseWare by shopping at Amazon.com! MIT OpenCourseWare offers direct links to Amazon.com to purchase the books cited in this course. Click on the Amazon logo to the left of any citation and purchase the book from Amazon.com, and MIT OpenCourseWare will receive up to 10% of all purchases you make. Your support will enable MIT to continue offering open access to MIT courses.

In addition to a thorough overview of 3.012, this page presents background information on the Department of Materials Science and Engineering (DMSE) undergraduate curriculum.

Overview of DMSE Undergraduate Curriculum (PDF)

3.012 is the introductory lecture class for sophomore students in Materials Science and Engineering, taken with 3.014 and 3.016 to create a unified introduction to the subject.

3.012 is an introduction to three topics fundamental to materials science and engineering: structure, bonding, and thermodynamics. These topics are not traditionally taught in tandem, though a structure course and thermodynamics course are usually part of the first core courses taken in a Materials Science and Engineering curriculum. The motivation for bringing these subjects together in 3.012 is to aid in teaching you the conceptual ties between these subjects. Bonding dictates structure, and structure in turn provides constraints on the thermodynamic properties of materials. These topics are intimately related and a full understanding of materials' synthesis, fabrication, and processing relies on bringing out these interconnections. In addition, it is enlightening to learn about the same materials from different viewpoints, to better appreciate the diverse perspectives we take when looking at materials science: What is the crystal structure of diamond? How does it affect its thermodynamics properties? How is it related to the nature of the bonding between carbon atoms? One then begins to see how these fundamental properties of materials are connected.

Many fascinating materials phenomena will become clear in the course of the class - Why are some materials easily polarized in one direction and not in another? Why are the heat capacities of very different crystals nearly equal at high temperatures? How do electrons "tunnel" through high barriers, and how can we exploit this to image atoms and molecules in real time? What prevents certain processes from occurring, while others proceed spontaneously? In addition, structure, bonding, and thermodynamic behavior underlie nearly every application of materials to a greater or lesser extent, and these topics play significant roles in the properties of materials that you will learn about in the coming 3 years.

The units reported in the course catalog: (5) (0) (10) appear confusing, given the course schedule (6 hours lecture per week, 2 hours recitation per week) - recall the units system is (hours lecture/recitation) (hours lab) (hours outside class). This is due to the integration of 3.012 with the laboratory course 3.014 - which runs 4 weeks of the term, and takes over the lecture time for 3.012 during lab weeks. Thus the course catalog units reflect an 'average' value measured over the entire term. In practice, you will have 2 hours lecture Monday Wednesday Friday, along with 2 recitations of 1 hour each on Tuesday and Thursday - during '3.012' weeks. During '3.014' lab weeks, 3.012 will not be in session. The schedule of the lecture/lab sessions is shown in the calendar section.

One of the following: 18.03, 18.034, 3.016

Two textbooks are required for this class.

• Engel, T., and P. Reid. Physical Chemistry. San Francisco, CA: Benjamin Cummings, 2005. ISBN: 9780805338423. [Note: this is the single-volume edition.]
• Allen, S. M., and E. L. Thomas. The Structure of Materials. New York, NY: J. Wiley & Sons, 1999. ISBN: 9780471000822.

The following supplemental textbooks are suggested, as alternative sources of background reading or practice problem-solving.

Structure and Bonding:

• Rohrer, G. Structure and Bonding in Crystalline Materials. New York, NY: Cambridge University Press, 2001. ISBN: 9780521663793.
• Atkins, P. W., and J. de Paula. Physical Chemistry. 7th ed. New York, NY: Oxford University Press, 2002. ISBN: 9780198792857.
• Nye, J. F. Physical Properties of Crystals: Their Representation by Tensors and Matrices. New York, NY: Oxford University Press, 1985. ISBN: 9780198511656.
• Mortimer, R. G. Physical Chemistry. 2nd ed. San Diego, CA: Elsevier, 2000. ISBN: 9780125083461.
• Thaller, B. Visual Quantum Mechanics. New York, NY: Springer-Verlag/TELOS, 2002. ISBN: 9780387989297.
• Bransden, B. H., and C. J. Joachain. Quantum Mechanics. 2nd ed. Upper Saddle River, NJ: Prentice Hall, 2000. ISBN: 9780582356917.
• Bransden, B. H., and C. J. Joachain. Physics of Atoms and Molecules. 2nd ed. Upper Saddle River, NJ: Prentice Hall, 2003. ISBN: 9780582356924.
• Petrucci, R. H., W. S. Harwood, and F. G. Herring. General Chemistry: Principles and Modern Applications. 8th ed. Upper Saddle River, NJ: Prentice Hall, 2001. ISBN: 9780130143297.

Thermodynamics and Statistical Mechanics:

• Dill, K. A., and S. Bromberg. Molecular Driving Forces . New York, NY: Routledge, 2002. ISBN: 9780815320517.
• Bent, H. A. The Second Law. New York, NY: Oxford University Press, 1965. ISBN: 9780195008296.
• Callen, H. B. Thermodynamics. New York, NY: John Wiley & Sons, 1960. ISBN: 9780471130352.
• Denbigh, K. G. The Principles of Chemical Equilibrium. 4th ed. New York, NY: Cambridge University Press, 1981. ISBN: 9780521281508.
• Mortimer, R. G. Physical Chemistry. 2nd ed. San Diego, CA: Elsevier, 2000. ISBN: 9780125083461.

Recitations are scheduled in two sections, held Tuesdays and Thursdays during lecture weeks (but not during 3.014 lab weeks). Recitations on Tuesdays will reinforce thermodynamics material, and Thursday recitations will cover bonding/structure material.

1. Composition of Final Grades:

Two of the exams are 2 hour quizzes given during lecture sessions, the last exam will fall during finals' week. The final exam is not cumulative.

2. Final Letter Grades:

Final letter grades will be determined by total weighted scores from the problems sets and 3 exams. The approximate score breakdown will be:

Note that these are the approximate score assignments: if your score falls at the border (e.g., between an A and B), we will look more carefully at your effort in the term to determine the final grade: did you improve over the course of the term? Were you diligent in doing the problem sets? The purpose of giving you these score assignments is to give you some indication of how you are doing as the term progresses.

3. Problem Sets:

Each problem set will contain 2-3 problems from structure/bonding and 2-3 problems from thermodynamics that will be graded. Problem sets can be turned in at recitation/lecture on the due date, or you may leave them in the drop box outside Prof. Irvine's office no later than 5 pm on the due date.

Important: Problem Set Turn-in Policy - The problems sets are a critical part of learning the material in this course. Generally, the problem set solutions will be provided immediately after the turn-in deadline. Late problem sets will not be accepted (they will be scored as zero points).

4. Exams:

Each exam will contain approximately half thermodynamics problems, and half structure/bonding questions. Two of the three exams will be given during lecture periods; see the calendar section for the detailed schedule. The last exam, though scheduled in finals week, will not be cumulative - it will only cover the lectures from Exam 2 onward.

Additional Syllabus information on the Thermodynamics Component (PDF)