| LEC # | TOPICS | SUBTOPICS | KEY DATES |
|---|---|---|---|
| Week 1 | |||
| 1 | I. Introduction | ||
| II. Structure and bonding | A) Formal charges B) Oxidation state C) d electron count D) Hapticity E) Coordination numbers and geometries F) d orbitals G) Ligands | ||
| 2 | Quiz on the periodic table | ||
| II. Structure and bonding (cont.) | G) Ligands (cont.) H) 18 electron "Rule" I) Counting electrons | ||
| III. Reactivity | A) Ligand substitution reactions | ||
| Week 2 | |||
| 3 | III. Reactivity (cont.) | B) Oxidative addition C) Reductive elimination D) Migratory insertion and elimination reactions | Problem set 1 due |
| Week 3 | |||
| 4 | III. Reactivity (cont.) | D) Migratory insertion (cont.) E) α-abstraction and β-abstraction F) Four-center reactions G) [2+2] Reactions H) Activation of L to external attack I) Reductive coupling | |
| 5 | III. Reactivity (cont.) | H) Activation of L to external attack (cont.) I) Reductive couplings (cont.) | Problem set 2 due |
| IV. Applications | A) Ziegler-natta polymerization B) TM carbenes | ||
| Week 4 | |||
| Exam | |||
| 6 | IV. Applications (cont.) | B) TM carbenes (cont.) | |
| Week 5 | |||
| 7 | IV. Applications (cont.) | B) TM carbenes (cont.) C) Hydrogenation | |
| 8 | IV. Applications (cont.) | D) Carbonylations E) Palladium-catalyzed coupling reaction | Problem set 3 due |
| Week 6 | |||
| 9 | IV. Applications (cont.) | E) Palladium-catalyzed coupling reaction (cont.) | |
| Final exam | |||